[Nature Communications]我室夏海平教授发表论文:Multiyne chains chelating osmium via three metal-carbon σ bonds

2017年12月06日

我室夏海平教授在 Nature Communications 上发表论文:Multiyne chains chelating osmium via three metal-carbon σ bonds

文章链接:https://www.nature.com/articles/s41467-017-02120-z

摘要:

Although the formation of metal–carbon σ bonds is a fundamental principle in organometallic chemistry, the direct bonding of one organic molecule with one metal center to generate more than two metal–carbon σ bonds remains a challenge. Herein, we report an aromaticity-driven method whereby multiyne chains are used to construct three metal–carbon σ bonds in a one-pot reaction under mild conditions. In this method, multiyne chains act as ligand precursors capable of chelating an osmium center to yield planar metallapolycycles, which exhibit aromaticity and good stability. The direct assembly of various multiyne chains with commercially available metal complexes or even simple metal salts provides a convenient and efficient strategy for constructing all carbon-ligated chelates on the gram scale.